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@article{Oloyede.2019,
 abstract = {A series of synthetically accessible ligands based on new 2-(R-sulfonamido)benzamide have been prepared (R = methyl for H3M; R =  4-toly for H3T and T2CN; R = 2,4,6-triisopropylphenyl for H3iP and HiPCN). The R-substituents were selected to vary in sizes. Allowing ligand H3iP and palladium acetate to stand in solvent leads to self-assembly of the well-defined solvent- and stoichiometry-controlled tetranuclear or hexanuclear coordination macromolecules Pd4(iP)2 and (PdHiP)6, which were analysed by Xray crystallography. It was observed that palladium active species for Suzuki coupling catalysis could be stabilized by these simple and synthetically assessable N-donor ligands as revealed by turnover frequencies reaching 5500 h-1. Electronic features of these N-donors appear to be more important than the steric properties.},
 author = {Oloyede, Hammed Olawale and G{\"o}rls, Helmar and {Orighomisan Woods}, Joseph Anthony and Plass, Winfried and Eseola, Abiodun Omokehinde},
 year = {2019},
 title = {N-donor 2-(Sulfonamido)benzamide ligands, their palladium(II) coordination species and C--C coupling catalysis efficiencies},
 keywords = {Catalyst design;C--C coupling;Homogeneous catalysis;N-Donor ligands;Palladium},
 pages = {336--344},
 volume = {1197},
 issn = {00222860},
 journal = {Journal of Molecular Structure},
 doi = {10.1016/j.molstruc.2019.07.054},
 file = {OLGOWO19:\\\\zufs.uni-jena.de\\CHEGE\\AGPlass\\Literatur\\Handapparat (Citavi 6)\\Handapparat\\Citavi Attachments\\OLGOWO19.pdf:pdf}
}